This paper firstly discusses the preparation methods of graphene/resin materials, and the characteristics of different methods were analyzed. The paper systematically elaborates the research status of graphene modifies resin materials and the mechanical, heat-resistant, conductive and friction-resistant properties, and analyzes the laws and mechanisms of the effect of adding graphene on the performance of resin materials. The results show that adding a small amount of graphene filler can improve the comprehensive performance of resin materials, and achieve a better improvement effects. Finally, based on the excellent properties of graphene / resin materials, the application prospects and future research direction were provided.